Binderless zeolite LTA beads with hierarchical porosity for selective CO2 adsorption in biogas upgrading

نویسندگان

چکیده

In the context of CO2 removal from biogas, a series binderless zeolite LTA adsorbents with macroscopic bead format (0.5–1.0 mm) and hierarchical porosity (i.e. zeolitic micropores being accessible through meso- macropores mainly in 10–100 nm range) was synthesized variety Si/Al ratios (1.2–3.9) using Amberlite IRA-900 anion-exchange resin beads as hard template. The CH4 adsorption capacity Na-form different were measured, reaching higher CO2/CH4 selectivity similar, yet slightly compared to commercial pellets containing binder. Subsequently, one subjected degrees ion-exchange (0–96%) KCl then tested CH4. best performance among all ion-exchanged achieved Na58K42-LTA beads, which gave very high (1540). Although essentially no adsorbed on these still substantial (1.9 mmol g−1 at 0.4 bar CO2, i.e. partial pressure biogas).

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ژورنال

عنوان ژورنال: Microporous and Mesoporous Materials

سال: 2022

ISSN: ['1873-3093', '1387-1811']

DOI: https://doi.org/10.1016/j.micromeso.2022.112208